) Hydrochloric acid, formic acid, nitric acid, hexanes, and toluene are all available in ACS grade through Carolina, which, with a bit of imagination, could turn into some spectacular experiments. (Toluene is, of course, a component in the production of TNT -- talk about an exothermic reaction.)
Laboratory equipment is also widely available. A simple search of the popular site Shopwiki.com reveals hundreds of beakers, pipettes, test tubes, alcohol burners, syringes, etc. More advanced items are also available, such as hot plates which automatically stir the contents of a flask placed on them, and a wealth of thermodynamic devices for pressure, temperature, and volume control.
Perhaps the best route for a truly interested young chemist to take is to begin with the CHEM 3000, working through its experiments and gaining insight, then proceed to a regime of self-education using the internet and libraries, and supplementing the capabilities of the CHEM 3000 with individually purchased chemicals and equipment. It is, apparently, still possible to burn one's house down and scare the wits out of one's mother while captivated by the wonders of chemistry; it is just not legal to sell a toy that provides the tools.
Empirically, it must be said that the progress of chemistry has not altogether halted for lack of chemistry sets to capture the minds of aspiring scientists....
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